You place 3.00 mol of NOCl(g) in a reaction vessel. Equilibrium is established with respect to… 1 answer below »

You place 3.00 mol of NOCl(g) in a reaction vessel. Equilibrium is established with respect to the decomposition reaction NOCl(g)  NO(g) + 1/2 Cl2(g).

a. Derive an expression for  in terms of the extent of reaction .

b. Simplify your expression for part (a) in the limit that  is very small.

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c. Calculate  and the degree of dissociation of NOCl in the limit that  is very small at 375 K and a pressure of 2.00 bar.

d. Solve the expression derived in part (a) using a numerical equation solver for the conditions stated in the previous part. What is the relative error in  made using the approximation of part (b)?

 

 

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