You are studying the Lindemann-type reaction Assume that you study the reaction using flash…

You are studying the Lindemann-type reaction

Assume that you study the reaction using flash photolysis. That is the reaction is initiated by absorption of a photon. And you may then measure the loss of A by measuring the absorption of a tuned laser beam as the reaction proceeds. You are able to gather short time data for the initial stage of the reaction. Your data for [A]/[A]0 as a function of time are in Table14.2.

You then conduct the same experiment for temperature controlled conditions between 280−300K. Since you know the order of the reaction you can now record data as half-times t1/2 defined as the time for one half of A to transform into B. Your data are in Table 14.3.

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(a) What is the order of the reaction? Why?

(b) What is the time constant τ for the reaction?

 

 

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