For water vapor, the van der Waals constants are a = 5.46 liter 2 atm/ mole 2 and b = 0.0305…

For water vapor, the van der Waals constants are a = 5.46 liter2 atm/ mole2 and b = 0.0305 liter/mole. (a) At a temperature of 500 K, the molar volume is about 7 liters when the pressure is 5.8 atm. For this particular system, estimate the degree of violation of equipartition.

(b) Repeat for water vapor when its molar volume is 0.1 liters under a pressure of 43 atm.

 

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